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Tris(dibenzylideneacetone)dipalladium 三(二亚苄基丙酮)二钯

规格: 98%,Pd>21.5%

CAS: 51364-51-3

产品编号: H93640

MDL: MFCD00013310

品牌: INFI

Chemical Name	Tris(Dibenzylideneacetone)Dipalladium
CAS Number	51364-51-3
Alfabeta Name	TRISDIBENZYLIDENEACETONEDIPALLADIUM ()
MDL Number	MFCD00013310
Synonym	Tris(dibenzylideneacetonyl)bis-palladium {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(dibenzylideneacetonyl)bis-palladium {} {} {} {} {} {} {}
PubChem Substance ID	9811564
Chemical Name Translation	三(二亚苄基丙酮)二钯
Reaxys-RN	14221398
LabNetwork Molecule ID	LN00173417
Beilstein Registry Number	87558761
InChI	InChI=1S/3C17H14O.2Pd/c318-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h31-14H;;/b3*13-11+,14-12+;;
Canonical SMILES	O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.[Pd][Pd]

GHS Symbol

Warnings	IRRITANT
WGK Germany	2
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition	2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P281 Use personal protective equipment as required. 使用所需的个人防护装备。 P302+P352 P305+P351+P338
Signal word	Warning
Hazard statements
H351 Suspected of causing cancer 怀疑致癌
Safety Statements
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Hazard Codes	Xn
Risk Statements
R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害 R36 Irritating to eyes 刺激眼睛 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

{ALF} Catalyst for Stille and Heck coupling reactions in supercritical CO2, in combination with, e.g. Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, L06941: Chem. Commun., 1397 (1998).

{ALF}

{ALF} Catalyzes the reduction of terminal allylic acetates or carbonates to 1-alkenes, with virtually complete regioselectivity: Synthesis, 623 (1986).

{ALF} For use in the coupling of aryl- or vinyltin reagents with allyl halides, see: J. Am. Chem. Soc., 105, 7173 (1983). For Suzuki coupling of boronic acids with carbapenem triflates, see: Tetrahedron Lett., 34, 3211 (1993).

{ALF} Stable source of phosphine-free Pd(0), useful in a variety of coupling reactions. Literature references to the use of either "Pd(dba)2" or "Pd2(dba)3" can normally be regarded as interchangeable since the catalyst is of somewhat variable composition depending on the exact method of preparation.

{ALF} In the presence of a chelating phosphine ligand and NaO-t-Bu, bromopyridines can be aminated: J. Org. Chem., 61, 7240 (1996):

{ALF} In the presence of allyl bromide, catalyzes the coupling of terminal alkynes to symmetrical diynes under phase-transfer conditions. The reaction is thought to involve a π-allyl Pd intermediate: Tetrahedron, 52, 1337 (1996).

{ALF} Catalyzes the hydroxycarbonylation of aryl and vinyl halides or triflates by lithium formate, to give carboxylic acids: Org. Lett., 5, 4269 (2003).

51364-51-3 H93640 Tris(dibenzylideneacetone)dipalladium
三(二亚苄基丙酮)二钯

化学属性

Mol. Formula	C51H42O3Pd2
Mol. Weight	915.72
Melting Point	152-155°C
Solubility	Soluble in chlorinated solvents
TSCA	No
Stability	对空气和湿度敏感
Appearance	purple pwdr.
Boiling Point	400.7°C at 760 mmHg
Redox	Reduction
Density	1.0

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Tris(dibenzylideneacetone)dipalladium 三(二亚苄基丙酮)二钯

规格: 98%,Pd>21.5%

化学属性

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