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Phenylphosphine 苯基膦

规格: 10 wt% in hexanes,SpcSeal
CAS: 638-21-1
产品编号: H91055
MDL: MFCD00002094
品牌: INFI
Chemical NamePhenylphosphine
Synonym phenyl-phosphine AURORA KA-1101 Phenylphosphinecolorlessliq 苯膦 Fenylfosfin PHENYLPHOSPHINE, 10% WEIGHT IN HEXANES Phenylphosphine,99%(10wt%inhexane) 苯基膦 Phenylphosphine,99% Phenylphosphine Phenylphosphineinhexane Phosphaniline PHPH2 Phosphine, phenyl- PHENYLPHOSPHINE (10% WT. IN HEXANE) phenylphosphane PHENYLPHOSPHINE Monophenylphosphine phenyl-phosphin phenylphosphine Phenylphosphine,99%(Sure/Sealbottle) Phenyl-phosphane
MDL NumberMFCD00002094
CAS Number638-21-1
PubChem Substance ID12519
Beilstein Registry Number0741946
EC Number211-325-4
Chemical Name Translation苯基膦
Wiswesser Line NotationPHHR
LabNetwork Molecule IDLN02124545
InChIInChI=1S/C6H7P/c7-6-4-2-1-3-5-6/h1-5H,7H2
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 38 ppm/4H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Sense Organs and Special Senses (Eye) - lacrimation
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,154,1969

WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H301+H311+H331
  • H319 Causes serious eye irritation 严重刺激眼睛
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSSZ2100000
    Precautionary statements
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P301+P310
    • P222 Do not allow contact with air. 不要与空气接触。
    • P422 Store contents under… 存储目录在…之下。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P231 Handle under inert gas. 在惰性气体中操作。
      Signal word Danger
      Safety Statements
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S33 Take precautionary measures against static discharges 对静电采取预防措施;
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
        Packing GroupI
        UN Number UN2845 2924 2845
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R48/20
        • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
        • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
        • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
        • R51/53
        • R17 Spontaneously flammable in air 在空气中能够自燃
        • R20 Harmful by inhalation 吸入有害
          Storage condition Air & Moisture Sensitive 储存温度 -20°C
          Hazard Codes F;T;N F,T,N F;T;N,N,T,F
          Hazard Class4.2
        • {uni_hamburg} Short: II/19b
        • Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules
        • Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G.
        • Editor: Hüttner, W.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/19b
        • Year: 1992
        • Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
        • ISBN: 3-540-54578-6
        • ISBN: 978-3-540-54578-1
        • Internet Resource: DOI:10.1007/b44334
        • RefComment: XI, 488 pages.
        • Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
        • {uni_hamburg} Short: II/19c
        • Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules
        • Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G.
        • Editor: Hüttner, W.
        • Source: Landolt-Börnstein, New Series
        • Volume: II/19c
        • Year: 1992
        • Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy
        • ISBN: 3-540-54893-9
        • ISBN: 978-3-540-54893-5
        • Internet Resource: DOI:10.1007/b44435
        • RefComment: 8 figs., XI, 295 pages.
        • Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplem
        • 638-21-1 H91055 Phenylphosphine
苯基膦

          化学属性

          Mol. FormulaC6H5PH2
          Mol. Weight110
          Vapor Density3.79 (vs air)
          Density1.001
          Boiling Point160°C
          Vapor Pressure760 mmHg ( 160 °C)
          Refractive index1.578
          TSCANo
          Flash Point165°F
          Stability对空气和水分敏感
          Appearance colorless liq.

          *以上化合物性质及应用等信息仅供参考