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Tetrachlorosilane 四氯化硅

规格: 99%, SpcSeal
CAS: 10026-04-7
产品编号: H85587
MDL: MFCD00011229
品牌: INFI
Chemical NameTetrachlorosilane
CAS Number10026-04-7
Reaxys-RN1361403
PubChem Substance ID87576528
MDL NumberMFCD00011229
Merck Number8500
EC Number233-054-0
Synonym Tetrachlorosilane chloridkremicity 四氯化硅 溶液 Silicon chloride (SiCl4) C 氯化硅 SILICON CHLORIDE Silane,tetrachloro- SILICON TETRACHLORIDE 四氯化硅/四氯硅烷 四氯矽烷 四氯化硅(IV), 99.998% (METALS BASIS) TETRACHOROSILANE CT1800 TETRACHLOROSILANE 氯化硅(IV) silicium(tetrachlorurede)(french) 四氯硅烷;四氯化矽;四氯甲硅烷;STC SILICON(IV) CHLORIDE Siliciumtetrachlorid SIC-L(TM) 四氯甲硅烷 四氯化矽 四氯化硅(IV), 99% (METALS BASIS) silicio(tetraclorurodi) Silane, tetrachloro- 四氯化硅,四氯四硅烷 STC 四氯化硅
Beilstein Registry Number2384789
Chemical Name Translation四氯化硅
InChIKeyFDNAPBUWERUEDA-UHFFFAOYSA-N
Wiswesser Line NotationSI G4
LabNetwork Molecule IDLN00164458
GHS Symbol
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 31,343,1949

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 15 gm/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   USKHAB Uspekhi Khimii. Progress in Chemistry.  For English translation, see
   RCRVAB. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1932-
   Volume(issue)/page/year: 38,2173,1969

RTECSVW0525000
UN Number 3265 1818
Signal word
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H301+H331
    Precautionary statements
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P305+P351+P338
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P403+P233
    • P305+P351+P338+P310
    • P301+P310
    • P301+P330+P331+P310
    • P303+P361+P353
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
    • P304+P340+P310
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
    • P308+P311
    • P303+P361+P353+P310+P363
    • P405 Store locked up. 上锁保管。
    • P234 Keep only in original container. 只保留在原来的容器中。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中,保持干燥;
        Risk Statements
        • R14 Reacts violently with water 遇水会猛烈反应
        • R35 Causes severe burns 会导致严重灼伤
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
        • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
        • R37 Irritating to respiratory system 刺激呼吸道
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
          Storage condition Moisture Sensitive 充氩保存
          WGK Germany2
          Hazard Codes C C,Xi
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
          Packing GroupII
          Hazard Class8
          Warnings 危化品目录(2015)
          Restrict 危险品
        • . Silicon tetrachloride (SiCl4) may be used as an intermediate in the manufacture of high purity silicon. High purity silicon derived from silicon tetrachloride may find major applications in the semiconductors industry and photovoltaic cells.
        • . High purity SiCl4 may be used to manufacture of optical fibers.
        • {SA}
        • Merck 14 ,8500
        • {SA}
        • Fieser 4 ,424 / Fieser 10 ,347 / Fieser 12 ,463 / Fieser 16 ,317
        • {SA}
        • Aldrich MSDS 1 , 1602:B / Aldrich MSDS 1 , 1602:A / Corp MSDS 1 (2), 3091:B / Corp MSDS 1 (2), 3091:C / RegBook 1 (3), 3323:J / Sax 6 , 2400
        • 10026-04-7 H85587 Tetrachlorosilane
四氯化硅

          化学属性

          Mol. FormulaSiCl4
          Mol. Weight170
          Refractive index1.4100 to 1.4150
          Density1.483
          Melting Point−70 °C
          TSCAYes
          Boiling Point57.6 °C
          Vapor Density5.86 (vs air)
          Vapor Pressure420 mmHg ( 37.7 °C)
          Flash Point57.6°C
          Solubility可混溶于苯、氯仿、石油醚等多数有机溶剂。
          Stability对湿度敏感
          Appearance colorless liq.

          *以上化合物性质及应用等信息仅供参考