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2,4,6-Triphenylpyrylium tetrafluoroborate 2,4,6-三苯基吡喃四氟硼酸盐

规格: 99%
CAS: 448-61-3
产品编号: H84484
MDL: MFCD00012001
品牌: INFI
Chemical Name2,4,6-Triphenylpyrylium tetrafluoroborate
MDL NumberMFCD00012001
CAS Number448-61-3
Beilstein Registry Number3586533
EC Number207-186-4
PubChem Substance ID9930615
Synonym 2,4,6-Triphenylpyrylium tetrafluoroborate {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triphenylpyrylium tetrafluoroborate {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation2,4,6-三苯基吡喃四氟化硼盐
InChIKeyVQYPWMWEJGDSTF-UHFFFAOYSA-N
Wiswesser Line NotationT6OJ BR& DR& FR &.B-F4 &3/19
LabNetwork Molecule IDLN00201404
InChIInChI=1S/C23H17O.BF4/c1-4-10-18(11-5-1)21-16-22(19-12-6-2-7-13-19)24-23(17-21)20-14-8-3-9-15-20;2-1(3,4)5/h1-17H;/q+1;-1
Canonical SMILESFB(F)F.C1(C2=CC=CC=C2)=CC(C3=CC=CC=C3)=CC(C4=CC=CC=C4)=[O+]1.[F-]
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02142

RTECSUZ1370000
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S22 Do not breathe dust 不要吸入粉尘;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R22 Harmful if swallowed 吞咽有害
    • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
      Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect fro
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P312
      • P302+P352
      • P304+P312
      • P304+P340
      • P305+P351+P338
      • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
      • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
      • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
      • P330 Rinse mouth. 漱口
      • P332+P313
      • P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
      • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
      • P403+P233
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H302 Harmful if swallowed 吞食有害
        • H302+H312+H332
        • H312 Harmful in contact with skin 皮肤接触有害
        • H315 Causes skin irritation 会刺激皮肤
        • H319 Causes serious eye irritation 严重刺激眼睛
        • H332 Harmful if inhaled 吸入有害
        • H335 May cause respiratory irritation 可能导致呼吸道刺激
          Signal word Warning
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Hazard Codes Xn
        • {ALF} Amines react with pyrylium salts to give N-alkylpyridinium salts. Since the pyridine can be displaced by a variety of nucleophiles, the result is that the amine has been converted to a useful alkylating species: J. Chem. Soc., Perkin 1, 418 (1979). Reviews: Tetrahedron, 36, 679 (1980); Angew. Chem. Int. Ed., 23, 420 (1984); Russ. Chem. Rev., 51, 469 (1982):
        • {ALF}
        • {ALF} For a review on use as an electron-transfer photosensitizer, see: Chem. Rev., 94, 1063 (1994).
        • 448-61-3 H84484 2,4,6-Triphenylpyrylium tetrafluoroborate
2,4,6-三苯基吡喃四氟硼酸盐

          化学属性

          Mol. FormulaC23H17BF4O
          Mol. Weight396.19
          Melting Point250-251 °C
          TSCANo
          Density1.0

          *以上化合物性质及应用等信息仅供参考