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Tantalum(V) chloride 氯化钽(V)

规格: 99.9% (metals basis)
CAS: 7721-01-9
产品编号: H78478
MDL: MFCD00011253
品牌: INFI
Chemical NameTantalum(V)
Synonym 5-氯化钽 5-氯化钽 99.8% 5-氯化钽 99.99% Pentachlorotantalum; Tantalum chloride; Tantalum pentachloride TANTALUM CHLORIDE TANTALUM(V) CHLORIDE TANTALUM(V) CHLORIDE, 99.99% TaCl5 Tantalum pentachloride Tantalum(V) chloride Tantalum(V) chloride, 99.8% metals basis Tantalum(V) chloride, 99.90% Tantalum(V)chloride,resublimed(99.99+%-Ta)PURATREM Tantalumchlorideanhydrous Tantalumchloridehighpurity tantalum (V) chloride tantalumchloride(tacl5) 五氯化钽 五氯化钽(V), 99.8% (METALS BASIS) 氯化鉭 氯化钽
CAS Number7721-01-9
PubChem Substance ID10269745
EC Number231-755-6
MDL NumberMFCD00011253
Merck Number9054
Beilstein Registry Number2384789
Chemical Name Translation氯化钽(V)
Reaxys-RN4123330
Wiswesser Line NotationTA G5
LabNetwork Molecule IDLN01341122
InChIInChI=1S/5ClH.Ta/h5*1H;/q;;;;;+5/p-5
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 75 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHOAX Archives of Industrial Hygiene and Occupational Medicine.  (Chicago,
   IL)  V.1-2(3), 1950.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 1,637,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHOAX Archives of Industrial Hygiene and Occupational Medicine.  (Chicago,
   IL)  V.1-2(3), 1950.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 1,637,1950

WGK Germany3
Hazard Codes 8 C
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
    Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
    RTECSWW5600000
    Precautionary statements
    • P234 Keep only in original container. 只保留在原来的容器中。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P312
    • P301+P330+P331
    • P301+P330+P331+P310
    • P303+P361+P353+P310+P363
    • P304+P340
    • P304+P340+P310
    • P305+P351+P338
    • P305+P351+P338+P310
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
    • P402+P404
    • P405 Store locked up. 上锁保管。
    • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
      • S8 Keep container dry 保持容器干燥;
        UN Number 3260
        Risk Statements
        • R14 Reacts violently with water 遇水会猛烈反应
        • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
        • R22 Harmful if swallowed 吞咽有害
        • R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
        • R34 Causes burns 会导致灼伤
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Moisture Sensitive
          Packing GroupII
          Hazard Class8
          Warnings 危化品目录(2015) 危险化学品
          Restrict 危险品
        • {ALF} In the presence of Zn metal, low-valent Ta complexes are formed with alkynes which react with carbonyl compounds to form (E)-allylic alcohols: J. Org. Chem., 55, 1707 (1990); 57, 321 (1992). Similarly, regioselective additions to alkenes can also be effected: J. Org. Chem., 59, 5852 (1994). With allylic alcohols, 1,4-dienes are formed: Chem. Lett., 315 (1995).
        • {SA} 2. Ogliaro F. et al. Inorg. Chem. 37 , 6199, (1998)
        • {ALF} In combination with silica, is a useful acid catalyst for, e.g. acetylation of alcohols: Tetrahedron Lett., 39, 3263 (1998), tetrahydropyranylation of alcohols and dithioacetalization of aldehydes: Tetrahedron, 53, 14997 (1997).
        • {uni_hamburg} Short: II/25A
        • 7721-01-9 H78478 Tantalum(V) chloride
氯化钽(V)

          化学属性

          Mol. FormulaTaCl5
          Mol. Weight358
          Density3.66
          Melting Point218 - 224 °C
          TSCAYes
          Boiling Point242 °C
          SolubilityDecomposes in water. Soluble in absolute alcohol and KOH
          Flash Point242 °C
          Appearance powder

          *以上化合物性质及应用等信息仅供参考