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Zirconium(IV) chloride 氯化锆

规格: 98%

CAS: 10026-11-6

产品编号: H71747

MDL: MFCD00011306

品牌: INFI

Chemical Name	Zirconium tetrachloride
Synonym	四氯化锆 Zirconium chloride (ZrCl4), (T-4)- Zirkoniumtetrachlorid Zirconium(IV) chloride Zirconium chloride zirconium (IV) chloride Zirconium tetrachloride Zirconium chloride (Zr2Cl8) Tetrachlorozirconium 四氯化锆 Zirkon(IV)-chlorid, wasserfrei 氯化锆(IV) Zirkon(IV)-chlorid wasserfrei Zirkontetrachlorid ZrCl₄ Tetrachlorozirconium Zirconium(IV) chloride, anhydrous 氯化锆
CAS Number	10026-11-6
PubChem Substance ID	24852962
EC Number	233-058-2
MDL Number	MFCD00011306
Merck Number	14,10174
Beilstein Registry Number	2384789
Chemical Name Translation	氯化锆
LabNetwork Molecule ID	LN00198098

GHS Symbol

WGK Germany	3
Hazard Codes	C
Hazard statements
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H302 Harmful if swallowed 吞食有害 H290 May be corrosive to metals 可能腐蚀金属。
Personal Protective Equipment	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECS	ZH7175000
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P305+P351+P338 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
Signal word	Danger Warning
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S30 Never add water to this product 切勿将水加入该产品中； S20 When using do not eat or drink 使用时，不得进食，饮水； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S8 Keep container dry 保持容器干燥；
UN Number	UN2503 2503
Risk Statements
R37 Irritating to respiratory system 刺激呼吸道 R14 Reacts violently with water 遇水会猛烈反应 R22 Harmful if swallowed 吞咽有害 R34 Causes burns 会导致灼伤 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R35 Causes severe burns 会导致严重灼伤
Storage condition	Moisture Sensitive 易吸潮，密封保存。充氩气保存充氩保存 Moisture Sensitive & Hygroscopic
Packing Group	III
Warnings	危化品目录(2015)
Restrict	危险品

用于制金属锆、颜料、纺织品防水剂、皮革鞣剂和分析试剂等。

{ALF} For a brief feature on uses of this reagent in synthesis, see: Synlett, 1073 (2003).

{ALF} Catalyzes the trans-hydrostannylation of acetylenes with Tri-n-butyltin hydride, A13298: J. Chem. Soc., Chem. Commun., 2405 (1995); J. Org. Chem., 61, 4568 (1996). Allylstannanes also add trans-selectively to acetylenes under similar conditions: J. Chem. Soc., Chem. Commun., 1513 (1996).

{ALF} Highly efficient and reusable catalyst for acetylation of phenols, thiols, amines and alcohols under solvent-free conditions, claimed to be superior to metal triflates: Synlett, 627 (2004).

{uni_hamburg} Short: II/25A

{ALF} Lewis acid. Promotes the rearrangement of hydroxy sulfones to ketones: J. Chem. Soc., Chem. Commun., 2289 (1994).

{ALF} Superior catalyst for the Fries rearrangement of aryl acetates, giving the least hindered ortho-acetyl phenol in high yields at ambient temperatures: Tetrahedron Lett., 37, 7659 (1996).

{ALD} Merck:14,10174

{ALF} In the presence of ZrCl4, chloromethyl ethers are formed under mild conditions from acid chlorides and trioxane or paraformaldehyde: Tetrahedron Lett., 43, 6317 (2002).

10026-11-6 H71747 Zirconium(IV) chloride
氯化锆

化学属性

Mol. Formula	ZrCl4
Mol. Weight	233.04
Density	2.78
TSCA	Yes
Melting Point	434 - 440 °C
Solubility	溶于冷水、乙醇、乙醚，不溶于苯、四氯化碳、二硫化碳。
Vapor Pressure	1 mmHg ( 190 °C)
Stability	对湿度敏感
Boiling Point	331 °C

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Zirconium(IV) chloride 氯化锆

规格: 98%

化学属性

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