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Nickel(II) Acetylacetonate 乙酰丙酮酸镍

规格: 98%

CAS: 3264-82-2

产品编号: H66709

MDL: MFCD00000024

品牌: INFI

Chemical Name	Nickel(II) acetylacetonate
CAS Number	3264-82-2
EC Number	221-875-7
Beilstein Registry Number	4157970
MDL Number	MFCD00000024
Reaxys-RN	4157970
PubChem Substance ID	9834912
Merck Number	6500
Synonym	Nickelous acetylacetonate {LY} Nickelous acetylacetonate {} {LY} Nickelous acetylacetonate {} {} {LY} Nickelous acetylacetonate {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Nickelous acetylacetonate
Chemical Name Translation	二乙酰丙酮镍
Wiswesser Line Notation	1V1V1 &-NI-
LabNetwork Molecule ID	LN02135171
InChI	InChI=1S/2C5H8O2.Ni/c21-4(6)3-5(2)7;/h23,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
Canonical SMILES	CC1=O[Ni+2]2(O=C(C)[CH-]1)O=C(C)[CH-]C(C)=O2

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CBCCT* "Summary Tables of Biological Tests," National Research Council
   Chemical-Biological Coordination Center.  (National Academy of Science
   Library, 2101 Constitution Ave., NW, Washington, DC 20418)
   Volume(issue)/page/year: 4,231,1952

Signal word	Danger
WGK Germany	3
Safety Statements
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
R22 Harmful if swallowed 吞咽有害 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用 R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Precautionary statements
P201 Obtain special instructions before use. 使用前获取专门指示。 P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。 P203 P233 Keep container tightly closed. ?保持容器密闭。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P281 Use personal protective equipment as required. 使用所需的个人防护装备。 P284 Wear respiratory protection.? 佩戴呼吸保护装置。 P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。 P301+P312 P301+P312+P330 P301+P317 P302+P352 P302+P352+P333+P313+P362+P364 P304+P340 P304+P340+P342+P311 P304+P341 P308+P313 P318 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P330 Rinse mouth. 漱口 P333+P313 P333+P317 P342+P311 P342+P316 P362+P364 P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。 P403 Store in a well-ventilated place. 储存在通风良好的地方。 P405 Store locked up. 上锁保管。 P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECS	SA2100000
Hazard statements
H302 Harmful if swallowed 吞食有害 H317 May cause an allergic skin reaction 可能导致皮肤过敏 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难 H350 May cause cancer 可能致癌 H351 Suspected of causing cancer 怀疑致癌
Hazard Codes	T T,Xi,Xn Xn
Personal Protective Equipment	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Storage condition	2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

有机反应的催化剂。

{uni_hamburg} Short: II/25D

{ALF} Catalyst for a variety of coupling reactions, e.g.: Coupling of Grignard reagents to give biaryls: J. Org. Chem., 41, 2252 (1976). Coupling of Grignards with silyl enol ethers of both aldehydes and ketones, to give alkenes. In contrast to Dichlorobis(triphenylphosphine)nickel(II), 13930, this reagent gives the thermodynamically more stable alkene: Tetrahedron Lett., 3915 (1980). Cross-coupling of alkyl iodides with dialkylzinc reagents tolerates a variety of functionalities: Angew. Chem. Int. Ed., 34, 2723 (1995).

{ALD} Merck: 14,6500

Beilstein: 1,IV,3677

{ALF} Aryl phosphates couple with Grignards (aryl tosylates do not couple under these conditions), affording high yields of biaryls: Tetrahedron Lett., 22, 4449 (1981). Cross-coupling of aryl chlorides with arylzincs also yields biaryls: Tetrahedron Lett., 39, 6441, 7275 (1998).

{ALD} Merck: 14,6500

{ALF} For a brief feature on uses of the reagent in synthesis, see: Synlett, 1042 (2005).

{ALF} For use in the condensation of active methylene compounds with lactims, see Isopropylidene malonate, A15603.

{ALF} Catalyst for the conjugate addition of 1,3-dicarbonyl compounds to various Michael acceptors: J. Org. Chem., 45, 1246 (1980).

3264-82-2 H66709 Nickel(II) Acetylacetonate
乙酰丙酮酸镍

化学属性

Mol. Formula	C10H14NiO4
Mol. Weight	256.91
Density	1.422
Melting Point	230 °C (dec.) (lit.)
Solubility	Soluble in water, alcohol, toluene
TSCA	Yes
Boiling Point	220°C at 11 mmHg
Flash Point	>200°C
Stability	对湿度敏感
Refractive index	1.57-1.64
Appearance	light green pwdr.

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Nickel(II) Acetylacetonate 乙酰丙酮酸镍

规格: 98%

化学属性

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