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Oxydi-2,1-phenylene)bis(diphenylphosphine 双[(2-二苯膦基)苯基]醚

规格: 98%
CAS: 166330-10-5
产品编号: H66210
MDL: MFCD00233863
品牌: INFI
Chemical NameBis(2-Diphenylphosphinophenyl)Ether
Synonym 双[(2-二苯膦基)苯基]醚 DPEPhos 双[(2-二苯膦基)苯基]醚 DPEphos 双(2-二苯基磷苯基)醚 DPEPhos
MDL NumberMFCD00233863
PubChem Substance ID87558783
EC Number000-000-0
CAS Number166330-10-5
Beilstein Registry Number7729718
Reaxys-RN7729718
Chemical Name Translation双(2-二苯基磷苯基)醚
LabNetwork Molecule IDLN00155010
GHS Symbol
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Signal word Warning
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P305+P351+P338
      • P332+P313
      • P305+P351+P338+P337+P313
      • P302+P350
      • P337+P313
      • P302+P352+P332+P313+P362+P364
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • 膦配体
        • {ALF} Bidentate ligand, investigated in Rh-catalyzed regioselective hydroformylation of olefins: Organometallics, 14, 3081 (1995). Reported by Buchwald to be highly effective in promoting the Pd-catalyzed N-arylation of anilines: Tetrahedron Lett., 39, 5327 (1998).
        • 166330-10-5 H66210 Oxydi-2,1-phenylene)bis(diphenylphosphine
双[(2-二苯膦基)苯基]醚

          化学属性

          Mol. FormulaC36H28OP2
          Mol. Weight539
          Melting Point184-187
          TSCANo
          Density1.422
          Appearance off-white pwdr.

          *以上化合物性质及应用等信息仅供参考