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Titanium(IV) chloride 四氯化钛

规格: 99% (99.9999%-Ti)

CAS: 7550-45-0

产品编号: H64688

MDL: MFCD00011267

品牌: INFI

Chemical Name	Titanium(IV) Chloride
Synonym	(t-4)-titaniumchloride(ticl4 TITANIUM ATOMIC SPECTROSCOPY STANDARD (TICL4) TITANIUM CHLORIDE TITANIUM(IV) CHLORIDE TITANIUM(IV) TETRACHLORIDE Tetrachlorotitanium Tetrachlorotitanium; Titanic chloride Tetrachlorure de titane Titane Titanic chloride Titanium chloride (TiCl4) (t-4)- Titanium tetrachl Titanium tetrachloride Titanium tetrachloride, Titanic chloride Titanium tetrachloride; Titanic chloride Titantetrachlorid tetrachloruredetitane titane(tetrachlorurede)(french) 四氯化钛四氯化钛(IV) 四氯化钛(IV) 溶液四氯化钛四氯化钛(IV), 99.0% MIN, TYPICALLY 99.6% 四氯化钛(禁运) 四氯化钛, 99.99% (METALS BASIS) 氯化钛氯化钛;TTC
CAS Number	7550-45-0
EC Number	231-441-9
MDL Number
Merck Number	9478
PubChem Substance ID	87558543
Beilstein Registry Number	2384789
Chemical Name Translation	四氯化钛
InChIKey	XJDNKRIXUMDJCW-UHFFFAOYSA-J
Wiswesser Line Notation	TI G4
LabNetwork Molecule ID	LN00220931

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,111,1982

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 400 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,111,1982

WGK Germany	2
Hazard Codes	6.1 C
Hazard statements
H301 Toxic if swallowed 吞食有毒 H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECS	XR1925000
Precautionary statements
P201 Obtain special instructions before use. 使用前获取专门指示。 P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P310 P303+P361+P353 P305+P351+P338 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word	Danger
UN Number	1838 3289 UN2924
Risk Statements
R14 Reacts violently with water 遇水会猛烈反应 R34 Causes burns 会导致灼伤 R37 Irritating to respiratory system 刺激呼吸道 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用 R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition	Moisture Sensitive 储存温度2-8℃,充氩保存 Flammables area 密封干燥保存。 0-10°C 0-10
Packing Group	II
Hazard Class	6.1/8
Warnings	危化品目录(2015)
Restrict	危险品

活化四氢吡咯以提高通过修正的波沃反应转化成相应的 α,α-二甲胺的转化率。促进 (S)-2-苄氧-3-戊酮在 THF 或 DME 中的高选择性羟醛缩合反应。

{ALF} In combination with NaI, for reduction of amine oxides and nitrones to amines: Chem. Ber., 123, 647 (1990); and sulfoxides to sulfides: Synthesis, 155 (1991). With Mg, for deoxygenation of aromatic N-oxides: Synthesis, 732 (1987). With LAH for the otherwise difficult reduction of sulfones to sulfides: J. Chem. Soc., Chem. Commun., 761 (1994). Reviews of low-valent titanium reagents in organic synthesis: Synthesis, 883 (1989); J. Organomet. Chem., 405, 1 (1991); J. Prakt. Chem./ Chem. Ztg., 337, 250 (1995).

{ALFA} Moderately strong Lewis acid with extremely wide application. Review of use in organic synthesis: Angew. Chem. Int. Ed., 16, 817 (1977). Brief feature: Synlett, 364 (2002).

{ALFA} Conversion of ketones to N-alkylimines: Org. Synth. Coll., 6, 818 (1988); Acta Chem. Scand., 46, 1211 (1992). Aldol condensation of aryl ketones with aryl aldehydes: Tetrahedron Lett., 28, 4135 (1987). Crossed aldol condensation of silyl enol ethers with carbonyl compounds: J. Am. Chem. Soc., 96, 7503 (1974); Org. Synth. Coll., 8, 323 (1993). ɑ-Tert-alkylation of ketones by reaction of the silyl enol ether with a tertiary halide: Org. Synth. Coll., 7, 424 (1990); review: Angew. Chem. Int. Ed., 21, 96 (1982); see also Zinc chloride, A16281. Michael addition of silyl enol ethers to ɑß-enones: Org. Synth. Coll., 8, 210 (1993). For conjugate allylation of ɑß-enones, see Allyltrimethylsilane, A14662. Regiospecific [3+2] annulation of enones with silylated allenes: J. Am. Chem. Soc., 103, 1604 (1981); Tetrahedron, 39, 935 (1983); Org. Synth. Coll., 8, 347 (1993):

{ALD} Merck: 14,9478

{ALFA} Examples of reactions mediated by TiCl4:

{ALFA} For use in a diastereoselective Mannich reaction, see: Helv. Chim. Acta, 67, 1593 (1984). Also used in combination with reducing agents for the generation of low-valent Ti species, which effect the reduction of various functional groups:

{ALFA} In combination with NaI, for reduction o

7550-45-0 H64688 Titanium(IV) chloride
四氯化钛

化学属性

Mol. Formula	TiCl4
Mol. Weight	190.00
Density	1.726
Boiling Point	135-136
Melting Point	-25
Refractive index	1.6059
Solubility	Soluble in dilute hydrochloric acid, alcohol and alkalies.
TSCA	Yes
Flash Point	8°(46°F)
Vapor Pressure	24.09 psi ( 55 °C)
Stability	对湿度敏感
Appearance	pale yellow liq.
Danger-Level	甲类
pH	-:A
Redox	-

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Titanium(IV) chloride 四氯化钛

规格: 99% (99.9999%-Ti)

化学属性

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