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Ferric acetylacetonate 三乙酰丙酮铁

规格: 98%

CAS: 14024-18-1

产品编号: H63835

MDL: MFCD00000020

品牌: INFI

Chemical Name	Iron, tris(2,4-pentanedionato-κO2,κO4)-, (OC-6-11)-
CAS Number	14024-18-1
EC Number	237-853-5
Beilstein Registry Number	4157960
MDL Number	MFCD00000020
PubChem Substance ID	87571482
Synonym	(Acetylacetonato)iron(III) (OC-6-11)-tris(2,4-pent (OC-6-11)-tris(2,4-pentane dionato-O,o')-iron 2,4-Eisen(III)-acetylacetonat 2,4-Pentanedione, iron(III) derivative 2,4-Pentanedione; Ferric acetylacetonate; Ferric acetylacetonate; 2,4-Pentanedione, iron(III) derivative 2,4-戊二酸铁(III) 4-戊二酮-O Acetope Fe(II) Fe(acac)3 Ferric acetylacetonate Ferric tris(acetylacetonate) Iron (III) 2,4-pentanedionate Iron acetylacetonate Iron acetylacetone Iron tris(2,4-pentanedionato) Iron tris(acetoacetonate) Iron tris(acetylacetonate) Iron(3+) acetylacetonate Iron(III) acetylacetonateTris(acetylacetonato)iron(III) Iron, tris(2,4-pentane Tris(acetylacetonato)-eisen(III) Tris(acetylacetonato)iron
Chemical Name Translation	三乙酰丙酮铁
Wiswesser Line Notation	D6O-FE-O BDJ D1 F1 B-& BD6O-FE-O BDJ D1 F1 B-&BD6O-FE-O BDJ D1 F1

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 76 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CHTHBK Chemotherapy (Basel).  (S. Karger Pub., Inc., 79 Fifth Ave., New
   York, NY 10003) V.13-    1968-  Volume(issue)/page/year: 16,371,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02372

Signal word	Warning
WGK Germany	3
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
R22 Harmful if swallowed 吞咽有害 R36 Irritating to eyes 刺激眼睛 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P312+P330 P305+P351+P338 P305+P351+P338+P337+P313 P332+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECS	NO8960000
Hazard statements
H302 Harmful if swallowed 吞食有害 H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes	Xn
Storage condition	密封保存

用作树脂交联剂合固化促进基；橡胶添加剂；石油裂解催化剂；燃料油添加剂，可改善润滑性和燃烧性；有机合成催化剂。

{ALF} In combination with Na metal at room temperature in benzene, cyano groups are cleaved from alkyl nitriles to give the corresponding hydrocarbons: J. Am. Chem. Soc., 93, 7113 (1971).

{uni_hamburg} Short: III/5b

{ALF} Catalyzes the nitration of non-activated arenes, e.g. halogenobenzenes, and moderately activated arenes, e.g. alkylbenzenes and naphthalenes under non-acidic, non-aqueous conditions with NO2 in the presence of O2; no nitration occurs in the absence of the Fe(III) catalyst: J. Chem. Soc., Perkin 1, 2385 (1996).

{ALF} Catalyst for the coupling of Grignard reagents with aryl halides: J. Am. Chem. Soc., 124, 13856 (2002); Org. Lett., 6, 1227 (2004), with vinyl sulfones to give alkenes: Tetrahedron Lett., 23, 2469 (1982); Tetrahedron, 44, 111 (1988), and with acyl halides to give ketones in good yield: Tetrahedron Lett., 25, 4805 (1984). Alkenyl halides couple with aryl Grignards to give 1-aryl alkenes: Synlett, 1901 (2001). For leading references and improved reaction conditions for the coupling of alkyl and aryl Grignards with a varirtety of enol triflates and acid chlorides, and also for selective monoalkylation of dichlroarenes and heteroarenes, see: J. Org. Chem., 69, 3743 (2004).

{ALD} Beilstein: 1,IV,3675

14024-18-1 H63835 Ferric acetylacetonate
三乙酰丙酮铁

化学属性

Mol. Formula	C15H21FeO6
Mol. Weight	353
Density	5.22
Melting Point	180 - 182 °C (dec.)(lit.)
TSCA	Yes
Solubility	2 G/L (20 ºC)
Stability	易吸潮
Boiling Point	110°C 2mm

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Ferric acetylacetonate 三乙酰丙酮铁

规格: 98%

化学属性

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