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Copper(II) trifluoromethanesulfonate 三氟甲烷磺酸铜(II)

规格: 98%

CAS: 34946-82-2

产品编号: H57213

MDL: MFCD00077492

品牌: INFI

Chemical Name	Copper(II) trifluoromethanesulfonate
MDL Number	MFCD00077492
Synonym	Copper(II) trifluoromethanesulfonate {LY} Copper(II) trifluoromethanesulfonate {} {LY} Copper(II) trifluoromethanesulfonate {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) trifluoromethanesulfonate {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	252-300-8
CAS Number	34946-82-2
Beilstein Registry Number	4028198
PubChem Substance ID	87577063
Reaxys-RN	4028198
Chemical Name Translation	三氟甲烷磺酸酮
LabNetwork Molecule ID	LN00224893
InChIKey	HRQFBGFAQQDQJD-UHFFFAOYSA-N
InChI	InChI=1S/2CHF3O3S.Cu/c22-1(3,4)8(5,6)7;/h2(H,5,6,7);/q;;+2/p-2
Canonical SMILES	O=S([O-])(C(F)(F)F)=O.[Cu+2]

GHS Symbol

Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Packing Group	II
UN Number	1759 3261
Risk Statements
R34 Causes burns 会导致灼伤
Storage condition	Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
WGK Germany	3
Precautionary statements
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P330+P331 P301+P330+P331+P310 P303+P361+P353+P310+P363 P304+P340 P304+P340+P310 P305+P351+P338 P305+P351+P338+P310 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P405 Store locked up. 上锁保管。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment	Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word	Danger
Hazard Codes	8 C
Hazard Class	8

有效催化把三甲基甲硅烷氰基添加到羰基化合物。

{ALF} Friedel-Crafts alkylation and acylation reactions of aromatics are also catalyzed: Tetrahedron, 57, 241 (2001).

{ALF} Widely used to generate carbenoid species from ɑ-diazo esters and ketones, via in situ reduction to the Cu(I) species: J. Am. Chem. Soc., 95, 3300 (1973). Preferred reagent for intramolecular cyclization of various diazo ketones: J. Org. Chem., 49, 11496 (1984). Also promotes the reaction between diazo esters and imines to give aziridines: J. Chem. Soc., Chem. Commun., 1 (1995).

{ALF} Catalyzes syn-selective aldol condensation of (Z)-silyl enol ethers with aldehydes: Chem. Lett., 959 (1997).

{ALF} Mild Lewis acid:

{ALF} Used catalytically, promotes dehydration of alcohols and diols to alkenes at ambient temperatures: Helv. Chim. Acta, 70, 607 (1987).

{ALF} For a brief feature on uses of the reagent in synthesis, see: Synlett, 1044 (2005).

34946-82-2 H57213 Copper(II) trifluoromethanesulfonate
三氟甲烷磺酸铜(II)

化学属性

Mol. Formula	Cu(CF3SO3)2
Mol. Weight	362
Melting Point	≥300 °C
TSCA	No
Density	1.422
Appearance	light green solid white to light green solid
Stability	hygroscopic

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Copper(II) trifluoromethanesulfonate 三氟甲烷磺酸铜(II)

规格: 98%

化学属性

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