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Tin(IV) chloride 四氯化锡

规格: 98% (as SnCl4), SpcSeal
CAS: 7646-78-8
产品编号: H48758
MDL: MFCD00011242
品牌: INFI
Chemical NameTin Tetrachloride
Synonym STANNIC CHLORIDE HYDRATE SnCl4 Stannane, tetrachloro- Stannic chloride Stannic chloride anhydrous Stannic chloride fuming Stannic chloride, anhydrous TIN CHLORIDE Tetrachlorostannane Tetrachlorotin Tin (IV) chloride anhydrous Tin chloride (SnCl4) Tin(IV) Chloride Pentahydrate Tin(IV) chloride Tin(IV) chloride anhydrous Tin(IV) chloride; Tetrachloro-stannane; Stannic chloride Tin(IV) tetrachloride Zinn(IV)-chlorid, wasserfrei Zinntetrachlorid etain(tetrachlorured’)(french) libaviusfumingspirit stannic chloride tin tetrachloride {} {} {} {} {} {} {} {Chemicalbook} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {Chemicalboo
CAS Number7646-78-8
PubChem Substance ID24287
EC Number231-588-9
MDL NumberMFCD00011242
Merck Number8774
Beilstein Registry Number2384789
Chemical Name Translation四氯化锡
LabNetwork Molecule IDLN00163756
InChIInChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
GHS Symbol
WGK Germany2
Hazard Codes 3 8 C F,T
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSXP8750000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P234 Keep only in original container. 只保留在原来的容器中。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P264+P265
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
    • P301+P310
    • P301+P330+P331
    • P302+P361+P354
    • P303+P361+P353
    • P304+P340
    • P304+P340+P310
    • P305+P351+P338
    • P305+P351+P338+P310
    • P305+P354+P338
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
    • P316
    • P317
    • P319
    • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P331 Do NOT induce vomiting.. 不要催吐。
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
    • P403+P233
    • P404 Store in a closed container. 贮存于密闭容器中。
    • P405 Store locked up. 上锁保管。
    • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Storage condition Moisture Sensitive Store at RT. 充氩保存 易吸潮，密封保存。 0-10°C 0-10
      UN Number 1827 2924
      Risk Statements
      • R11 Highly flammable 非常易燃
      • R34 Causes burns 会导致灼伤
      • R50/53
      • R52/53
      • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
      • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
        Safety Statements
        • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
        • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
        • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
          Packing GroupII
          Hazard Class8
          Warnings 危化品目录(2015)
          Restrict 剧毒
        • A starting material for organotin compounds
        • {ALFA} Lewis acid catalyst, e.g. for intermolecular: Org. Synth. Coll., 2, 8 (1943), or intramolecular: Org. Synth. Coll., 4, 900 (1963) Friedel-Crafts acylations.
        • {ALFA} In the presence of tri-n-butylamine, reacts with terminal alkynes to give reactive alkynyltrichlorotin reagents, which effect alkynylation of aldehydes, acetals and enones: Chem. Lett., 2479 (1992).
        • {uni_hamburg} Short: II/25A
        • {ALD} Merck: 14,8774
        • {ALFA} Mediates condensations with silyl enol ethers, see, e.g.: Org. Synth. Coll., 7, 414 (1990); 8, 578 (1993).
          • 7646-78-8 H48758 Tin(IV) chloride 四氯化锡

          化学属性

          Mol. FormulaCl4Sn
          Mol. Weight261
          Boiling Point114 °C(lit.)
          Density0.874
          Melting Point−36 - −30 °C(lit.)
          Refractive index1.512
          SolubilitySoluble in alcohol, CCl4, benzene, toluene, and acetone. Soluble in water with much heat evolution
          TSCAYes
          Vapor Density9 (vs air)
          Vapor Pressure10 mmHg ( 10 °C)
          Flash Point34 °F
          Stability易吸潮
          Appearance colorless liq.
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性质及应用等信息仅供参考

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