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Phosphorus oxychloride 三氯氧磷(V)

规格: 99.5%

CAS: 10025-87-3

产品编号: H48627

MDL: MFCD00011443

品牌: INFI

Chemical Name	Phosphorus Oxychloride
Synonym	Phosphoryl trichloride 三氯氧磷(V) trichlorophosphorus oxide Phosphorus oxide trichloride Phosphorus(V) trichloride oxide phosphorus chloride oxide(pocl3) Phosphoric trichloride; Phosphoryl chloride; Phosphoryl oxychloride; Phosphoryl trichloride Phosphorylchlorid Phosphorus oxytrichloride phosphorus trichloride oxide Phosphoroxychlorid Phosphorusoxy chloride Phosphorylchlorid FO Optipur® Phosphorus oxide chloride Phosphorsäuretrichlorid Trichlorophosphorus oxide Phosphoroxichlorid Phosphortrichloridoxid Phosphorous chloride oxide (POCl3) Phosphoroxychloride phosphoric trichloride phosphoryl chloride Phosphorus chloride oxide (PCl3O) trichlorophosphine oxide Phosphoric chloride phosphoryl trichloride Phosphorus (V) trichloride oxide Phosphoryltrichlorid Phosphorus chloride oxide (POCl3) Phosphoroxidtrichlorid Oxychlorid fosforecny Phosphoroxidchlorid Phosphonyl trichloride Phosphorus monoxide trichloride Phosphorus oxychloride Phosphoroxytrichloride Fosforoxychlorid Trichlorophosphine oxide
EC Number	233-046-7
MDL Number	MFCD00011443
PubChem Substance ID	24859264
CAS Number	10025-87-3
Merck Number	14,7349
Chemical Name Translation	三氯氧磷
Wiswesser Line Notation	P O G3

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 53 ppm/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Behavioral - irritability
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   25,470,1964

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Liver - other changes
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534840

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 36 mg/kg
TOXIC EFFECTS :
   Gastrointestinal - other changes
   Liver - other changes
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534840

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 32 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologick

WGK Germany	1
Hazard statements
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤 H330 Fatal if inhaled 吸入致命 H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官 H302 Harmful if swallowed 吞食有害
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECS	TH4897000
Precautionary statements
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P284 Wear respiratory protection.? 佩戴呼吸保护装置。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P305+P351+P338
Signal word	Danger
Packing Group	I
UN Number	1810 UN1810
Risk Statements
R48/23 R26 Very toxic by inhalation 吸入极毒 R14 Reacts violently with water 遇水会猛烈反应 R22 Harmful if swallowed 吞咽有害 R35 Causes severe burns 会导致严重灼伤 R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
Safety Statements
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition	Moisture Sensitive
Hazard Codes	T+;C T+,C
Warnings	危化品目录(2015)
Restrict	危险品

{uni_hamburg} Short: II/25A

Title: Structure Data Of Free Polyatomic Molecules: Inorganic Molecules

Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N.

Editor: Kuchitsu, K.

Source: Landolt-Börnstein, New Series

Volume: II/25A

Year: 1998

Keyword: Free Polyatomic Molecules; Inorganic Molecules; Molecules

ISBN: 3-540-61713-2

ISBN: 978-3-540-61713-6

Internet Resource: DOI:10.1007/b59072

RefComment: VII, 359 pages. Hardcover

Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.

{uni_hamburg} Short: II/5

Title: Molecular Acoustics

Author: Schaaffs, W.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: II/5

Year: 1967

ISBN: 3-540-03897-3

ISBN: 978-3-540-03897-9

Internet Resource: DOI:10.1007/b19950

RefComment: 321 figs., XII, 286 pages, Hardcover

{uni_hamburg} Short: III/20b

Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb

Author: Chihara, H.; Nakamura, N.

Editor: Hellwege, K.-H.; Hellwege, A.M.

Source: Landolt-Börnstein, New Series

Volume: III/20b

Year: 1988

Keyword: NQR

ISBN: 3-540-18483-X

ISBN: 978-3-540-18483-6

Internet Resource: DOI:10.1007/b86664

RefComment: IX,717 pages. Hardcover

Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,

10025-87-3 H48627 Phosphorus oxychloride
三氯氧磷(V)

化学属性

Mol. Formula	Cl3OP
Mol. Weight	153.35
Density	1.675
Vapor Density	5.3 (vs air)
Boiling Point	107 °C
Vapor Pressure	104 mmHg ( 50 °C)
Melting Point	2°C
Refractive index	1.460
TSCA	Yes
Solubility	起反应 EXOTHERMICALLY
Appearance	colorless liq.
Stability	moisture sensitive
pH	:A
Flash Point	105.8°C

*以上化合物性质及应用等信息仅供参考

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催化剂

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Phosphorus oxychloride 三氯氧磷(V)

规格: 99.5%

化学属性

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