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1-(Trimethylsiloxy)cyclohexene 1-(三甲基硅氧基)环己烯

规格: 98%
CAS: 6651-36-1
产品编号: H48553
MDL: MFCD00001541
品牌: INFI
Chemical Name(Cyclohex-1-en-1-yloxy)trimethylsilane
CAS Number6651-36-1
Alfabeta NameTRIMETHYLSILYLOXYCYCLOHEXENE 1()-
MDL NumberMFCD00001541
Synonym 1-Cyclohexenyloxytrimethylsilane {LY} 1-Cyclohexenyloxytrimethylsilane {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Cyclohexenyloxytrimethylsilane {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID81161
EC Number229-675-1
Beilstein Registry Number1859394
Reaxys-RN1859394
Chemical Name Translation1-环己烯氧基三甲基硅烷
InChIKeySBEMOANGDSSPJY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00160539
Canonical SMILESO(C1=CCCCC1)[Si](C)(C)C
InChIInChI=1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
GHS Symbol
Warnings IRRITANT
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Signal word Warning {} {} {} {} {} {} {TCI}
    UN Number 1993 UN 1993 3/PG 3 UN1993
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P241+P242+P243
    • P242 Use only non-sparking tools. 只能使用无火花工具。
    • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P303+P361+P353
    • P370+P378
    • P403+P235
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Risk Statements
      • R10 Flammable 易燃
        Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
        Packing GroupIII
        Hazard Codes F
        Hazard Class3
        Safety Statements
        • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
        • {SA}
        • Aldrich MSDS 1 , 519:D / Corp MSDS 1 (1), 969:A / FT-IR 2 (3), 4369:A / FT-NMR 1 (3), 662:A / IR-Spectra (3), 1538:G / IR-Spectra (2), 1316:G / NMR-Reference 2 (2), 991:D / RegBook 1 (2), 2969:G / Structure Index 1 , 470:B:1 / Vapor Phase 3 , 1642:C
        • {ALF} Silyl enol ethers undergo crossed aldol condensations with aldehydes and ketones: J. Am. Chem. Soc., 96, 7503 (1974); for tabulated results, see: Org. Synth. Coll., 8, 323 (1993):
        • {ALF}
        • {ALF} Condensation with aldehydes is also promoted by F-, particularly TBAF: J. Org. Chem., 48, 932 (1983).
        • {ALF} The Lewis acid-catalyzed condensation with nitroalkenes leads to 1,4-diketones: J. Am. Chem. Soc., 98, 4679 (1976); Org. Synth. Coll, 7, 414 (1990).
        • {ALF} For reviews of the chemistry of silyl enol ethers, see: Synthesis, 91 (1977); 85 (1983).
        • 6651-36-1 H48553 1-(Trimethylsiloxy)cyclohexene
1-(三甲基硅氧基)环己烯

          化学属性

          Mol. FormulaC9H18OSi
          Mol. Weight170.32
          Refractive index1.4450 to 1.4480
          Boiling Point64-65 °C at 15 mmHg
          Density0.875
          Flash Point41°C(lit.)
          TSCAYes

          *以上化合物性质及应用等信息仅供参考