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Copper(I) bromide 溴化亚铜

规格: 98.5%
CAS: 7787-70-4
产品编号: H48354
MDL: MFCD00010969
品牌: INFI
Chemical NameCopper(I) bromide
Synonym Copper(I) bromide {LY} Copper(I) bromide {} {LY} Copper(I) bromide {} {} {LY} Copper(I) bromide {} {} {} {LY} Copper(I) bromide {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00010969
PubChem Substance ID24593
CAS Number7787-70-4
EC Number232-131-6
Beilstein Registry Number2384789
Merck Number14,2659
Chemical Name Translation溴化亚铜
LabNetwork Molecule IDLN00194961
InChIInChI=1S/BrH.Cu/h1H;/q;+1/p-1
Canonical SMILES[Cu]Br
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Hazard statements
    • H302 Harmful if swallowed 吞食有害
    • H312 Harmful in contact with skin 皮肤接触有害
    • H315 Causes skin irritation 会刺激皮肤
    • H318 Causes serious eye damage 严重伤害眼睛
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
    • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
    • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
      Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S37 Wear suitable gloves 戴适当手套；
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
      • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        Risk Statements
        • R22 Harmful if swallowed 吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition RT, stored under nitrogen, away from moisture {LY} RT, stored under nitrogen, away from moisture Store at room temperature {} {LY} RT, stored under nitrogen, away from moisture {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitroge
          UN Number UN3077 3260
          Packing GroupIII
          Hazard Codes Xi
          Hazard Class8
        • 有机反应催化剂。
        • {ALFA} Reaction of Grignard reagents with aromatic nitriles is potentially a useful route to ketones via the imine. However, in the absence of a catalyst, reaction is generally very slow and gives indifferent yields. In the presence of CuBr, tert-butylmagnesium chloride reacts readily with benzonitrile to give tert-butyl phenyl ketone in 94% yield: J. Org. Chem., 52, 3901 (1987).
        • {ALFA} Precursor of organocopper reagents. For reviews, see: Org. React., 22, 253 (1975); 41, 135 (1992); Synthesis, 63 (1972); Tetrahedron, 45, 349 (1989).
        • {ALFA} Catalyst for 1,4-addition of Grignard reagents to enones: J. Org. Chem., 27, 707 (1962); Org. Synth. Coll., 8, 522 (1993).
        • {ALD} Merck: 14,2659
        • {uni_hamburg} Short: II/24A
          • 7787-70-4 H48354 Copper(I) bromide 溴化亚铜

          化学属性

          Mol. FormulaBrCu
          Mol. Weight143.45
          Density4.69
          Melting Point501 - 507 °C(lit.)
          SolubilitySlightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, NH4OH
          TSCAYes
          Boiling Point1345 °C
          Refractive index2.116
          Stability对光和空气敏感，充氩操作和储存
          Flash Point1345°C
          Appearance off-white to pale-green pwdr.

          *以上化合物性质及应用等信息仅供参考

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