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Palladium(II) trifluoroacetate 三氟乙酸钯

规格: 98%

CAS: 42196-31-6

产品编号: H41066

MDL: MFCD00013204

品牌: INFI

Chemical Name	Palladium(II) Trifluoroacetate
Synonym	2,7-DICHLORO-9-FLUORENONE, TECH., 90% PALLADIUM (II) TRIFLUOROACETATE 97+% PALLADIUM TRIFLUOROACETATE Palladium(II) trifluoroacetate, min. 97% Palladium(II)trifluoroacetate,min.97% Pd(TFA)2 Trifluoroacetic acid palladium(II) salt 三氟乙酸钯(II) 盐
MDL Number	MFCD00013204
PubChem Substance ID	2733347
CAS Number	42196-31-6
Reaxys-RN	15732764
EC Number	250-023-7
Beilstein Registry Number	2384789
Chemical Name Translation	三氟乙酸钯
LabNetwork Molecule ID	LN00197814
InChI	InChI=1S/2C2HF3O2.Pd/c23-2(4,5)1(6)7;/h2(H,6,7);/q;;+2/p-2

GHS Symbol

WGK Germany	3
Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P302+P352+P332+P313+P362+P364 P305+P351+P338 P305+P351+P338+P337+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Hazard statements
H315 Causes skin irritation 会刺激皮肤 H319 Causes serious eye irritation 严重刺激眼睛 H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes	Xi
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Gloves
Signal word	Warning
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition	Hygroscopic

{ALFA} Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allylpalladium(II) chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)phosphine, L13329, has been found to give superior results to Palladium(II) acetate, 10516, or Tris(dibenzylideneacetone)dipalladium(0), 12760, as a Pd source in Heck, Stille and Suzuki coupling reactions carried out in supercritical CO2: Tetrahedron Lett., 40, 2221 (1999).

{SA} Kato, K.; Motodate, S. et al. Angew. Chem. Int. Ed. Engl. 48 , 3326, (2009)

{SA} 2. Science 316 , 1172, (2007) 摘要

{SA} Tetrahedron Lett. 25 , 4187, (1984)

{ALF} Readily forms π-allylpalladium dimers with acyclic alkenes: J. Am. Chem. Soc., 102, 3572 (1980). See also Allylpalladium(II) chloride dimer, 10005. In combination with a phosphine ligand, particularly Tri(2-furyl)phosphine, L13329, has been found to give superior results to Palladium(II) acetate, 10516, or Tris(d

{SA} R'kyek, O.; Halland, N. et al. Chem. Eur. J. 16 , 9986, (2010)

42196-31-6 H41066 Palladium(II) trifluoroacetate
三氟乙酸钯

化学属性

Mol. Formula	C4F6O4Pd
Mol. Weight	332
Melting Point	220 °C
TSCA	No
Density	1.422
Redox	Reduction

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Palladium(II) trifluoroacetate 三氟乙酸钯

规格: 98%

化学属性

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