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1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔

规格: 98%
CAS: 6224-91-5
产品编号: H38919
MDL: MFCD00009271
品牌: INFI
Chemical NameTrimethyl(prop-1-yn-1-yl)silane
CAS Number6224-91-5
Synonym Trimethyl(prop-1-yn-1-yl)silane {LY} Trimethyl(prop-1-yn-1-yl)silane {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Trimethyl(prop-1-yn-1-yl)silane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
PubChem Substance ID87576914
EC Number228-314-5
Beilstein Registry Number1071311
MDL NumberMFCD00009271
Reaxys-RN1071311
Chemical Name Translation1-(三甲基硅基)丙炔
InChIKeyDCGLONGLPGISNX-UHFFFAOYSA-N
LabNetwork Molecule IDLN00194943
Canonical SMILESCC#C[Si](C)(C)C
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes 3 F;Xi
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
    • P241+P242+P243
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P302+P352+P332+P313+P362+P364
    • P303+P361+P353
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P332+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    • P370+P378
    • P403+P235
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S29 Do not empty into drains 不要排入下水道；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          UN Number 1993 UN 1993 3/PG 2
          Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {}
          Packing GroupII
          Hazard Class3
        • 经由钯催化的碳环合成高取代的茚类； 铑催化的和二溴苯硼酸的反应合成二氢茚酮(indenones)；在Cp2Zr(H)CI存在下把醛转化成1,3-二烯烃等等。
        • {TRC} Zlotos, D., et al.: J. Med. Chem., 47, 3561 (2004),
        • {TRC} Falck, J., et al.: Bioorg. Med. Chem. Lett., 14, 4987 (2004),
        • {SA} J. Am. Chem. Soc. 129 , 5766, (2007) 摘要
        • {SA} Beil. 4 ,IV,3938
        • {ALD} Beilstein: 4,IV,3938
        • {uni_hamburg} Short: III/35F
        • {ALF} Alkylation of the lithio-derivative proceeds with only a small amount of allylic rearrangement to the allene, and is thus a useful route to substituted terminal alkynes: Tetrahedron Lett., 5041 (1968):
          • 6224-91-5 H38919 1-(Trimethylsilyl)propyne 1-(三甲基硅基)丙炔

          化学属性

          Mol. FormulaC6H12Si
          Mol. Weight112.24
          Refractive index1.4190 to 1.4210
          Boiling Point99-100°C at 760 mmHg
          Density0.758
          Flash Point4°C
          TSCANo
          Melting Point-69°C
          Vapor Density>;1 (vs air)

          *以上化合物性质及应用等信息仅供参考

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