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Dimethyl phosphite 亚磷酸二甲酯

规格: 98%

CAS: 868-85-9

产品编号: H32856

MDL: MFCD00044633

品牌: INFI

Chemical Name	Dimethyl Phosphite
CAS Number	868-85-9
PubChem Substance ID	6327114
EC Number	212-783-8
Beilstein Registry Number	1697490
MDL Number	MFCD00044633
Synonym	Dimethyl hydrogenphosphonate Phosphonic acid, dimethyl ester Dimethyl phosphonate Dimethylfosfit Dimethylfosfonat Dimethyl hydrogen phosphite Methyl phosphite, (MeO)2(HO)P 亚磷酸二甲酯 Dimethyl phosphite (DMP) dimethylphosphorousacid phosphonic acid dimethyl ester PHOSPHONIC ACID DIMETHYL ESTER (CH3O)2PHO Dimethylhydrogenphosphit NCI-C54773 dimethylphosphite DIMETHYL PHOSPHONATE bis(hydroxymethyl)phosphineoxide 亚磷酸二甲酯, 98+% DIMETHYL HYDROGEN PHOSPHITE Bis(hydroxymethyl)phosphine oxide Hydrogen dimethyl phosphite dimethylacidphosphite Dimethylester kyseliny fosforite dimethylesterkyselinyfosforite Dimethylhydrogenphosphite Dimethyl hydrogen phosphonate {uni_ha Phosphorous acid dimethyl ester dimethylhydrogenphosphonate Dimethyl ester of phosphonic acid Phosphorous acid, dimethyl ester Dimethyl phosphorous acid DMP Dimethyl hydrogen phosphite; Dimethyl phosphite Dimethylphosp Dimethoxyphosphine oxide dimethylesterkyselinifosforite(czech) Dimethylphosphorous acid Dimethyl acid phosphite Dimethylphosphit DIMETHYL PHOSPHITE Phosphonsäuredimethylester Dimethyl phosphate 磷酸二甲酯 dimethoxyphosphineoxide Phosphorigsäuredimethylester PHOSPHOROUS ACID DIMETHYL ESTER Methyl phosphonate ((MeO)2HPO)
Chemical Name Translation	亚磷酸二甲酯
Wiswesser Line Notation	1OPHO&O1
InChI	InChI=1S/C2H6O3P/c1-4-6(3)5-2/h1-2H3/q+1

GHS Symbol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 103 gm/kg/2Y-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Gastrointestinal - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-287,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2970 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPEC

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 900 mg/kg
TOXIC EFFECTS :
   Autonomic Nervous System - other (direct) parasympathomimetic
   Lungs, Thorax, or Respiration - respiratory stimulation
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 36(4),22,1992

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ALBRW* Albright & Wilson Inc.  (P.O. Box 26229, Richmond, VA 23260-6229)
   Volume(issue)/page/year: #OPB-3,1984

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3040 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTPTR* Nat

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 1500 mg/kg/3D (Continuous)
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   21,160,1993

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 1700 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 7500 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 250 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 1600 mg/L
REFERENCE :
   SCIEAS Science.  (American Assoc. for the Advancement of Science, 1333 H
   St., NW, Washington, DC 20005)  V.1-    1895-  Volume(issue)/page/year:
   236,933,1987

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 2100 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th

WGK Germany	1
Hazard statements
H311 Toxic in contact with skin 皮肤接触中毒 H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	Xn
RTECS	SZ7710000
Precautionary statements
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P305+P351+P338
Signal word	Danger
Risk Statements
R21 Harmful in contact with skin 与皮肤接触有害 R36 Irritating to eyes 刺激眼睛 R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性 R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用 R10 Flammable 易燃
Safety Statements
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Storage condition	Moisture Sensitive
UN Number	UN 3278 6.1/PG 3 1992
Packing Group	III
Hazard Class	3.2
Restrict	监控化学品

{SA}

Beil. 1 ,IV,1255

{SA}

Fieser 1 ,293 / Fieser 4 ,188 / Fieser 5 ,258

{SA}

Aldrich MSDS 1 , 795:A / Corp MSDS 1 (1), 1408:B / FT-NMR 1 (1), 1471:A / IR-Spectra (3), 549:D / IR-Spectra (2), 487:A / NMR-Reference 2 (2), 864:C / RegBook 1 (1), 1097:E / Sax 6 , 1167 / Structure Index 1 , 169:B:8

{uni_hamburg} Short: III/35A

Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Boron-11 and Phosphorus-31

Author: Gupta, R.R.; Jain, M.; Pardasani, P.; Pardasani, R.T.; Pelter, A.

Editor: Gupta, R.R.; Lechner, M.D.

Source: Landolt-Börnstein, New Series

Volume: III/35A

Year: 1997

ISBN: 3-540-60366-2

ISBN: 978-3-540-60366-5

Internet Resource: DOI:10.1007/b53033

RefComment: VIII, 242 pages. With CD-ROM. Hardcover

Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

{uni_hamburg} Short: III/35C4

Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds

Author: Gupta, R.R.; Platzer, N.

Editor: Gupta, R.R.; Lechner, M.D.

Source: Landolt-Börnstein, New Series

Volume: III/35C4

Year: 2001

Keyword: Hydrogen 1; Nuclear Magnetic Resonance

ISBN: 3-540-41059-7

ISBN: 978-3-540-41059-1

Internet Resource: DOI:10.1007/b76570

RefComment: VII, 299 pages. With CD-ROM. Hardcover

Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonanc

868-85-9 H32856 Dimethyl phosphite
亚磷酸二甲酯

化学属性

Mol. Formula	C2H7O3P
Mol. Weight	110.06
Refractive index	n20/D 1.402(lit.)
Boiling Point	170-171 °C(lit.)
Density	1.2
Flash Point	85 ºF
TSCA	Yes
Appearance	1.4009，相对密度1.2004，易溶于醇、醚等有机溶剂。本品为无色油状液体，b.p.265℃，n D 20

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

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Dimethyl phosphite 亚磷酸二甲酯

规格: 98%

化学属性

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