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Methyldiphenylphosphine oxide 甲基二苯基氧化膦

规格: 98%
CAS: 2129-89-7
产品编号: H29828
MDL: MFCD00002081
品牌: INFI
Chemical NameMethyldiphenylphosphine oxide
Synonym Methyldiphenylphosphine oxide {LY} Methyldiphenylphosphine oxide {} {LY} Methyldiphenylphosphine oxide {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyldiphenylphosphine oxide {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00002081
CAS Number2129-89-7
PubChem Substance ID75041
EC Number218-346-8
Beilstein Registry Number957291
Reaxys-RN957291
Chemical Name Translation甲基二苯基氧化膦
InChIKeyPEGCITODQASXKH-UHFFFAOYSA-N
InChIInChI=1S/C13H13OP/c1-15(14,12-8-4-2-5-9-12)13-10-6-3-7-11-13/h2-11H,1H3
LabNetwork Molecule IDLN00198535
Canonical SMILESCP(C1=CC=CC=C1)(C2=CC=CC=C2)=O
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 840 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KHFZAN Khimiko-Farmatsevticheskii Zhurnal.  Chemical Pharmaceutical Journal.
    For English translation, see PCJOAU.  (V/O Mezhdunarodnaya Kniga, 113095
   Moscow, USSR)  V.1-    1967-  Volume(issue)/page/year: 24(4),22,1990

WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337 If eye irritation persists: 如果眼睛刺激持续
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Signal word Warning
    Hazard statements
    • H302 Harmful if swallowed 吞食有害
    • H312 Harmful in contact with skin 皮肤接触有害
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H332 Harmful if inhaled 吸入有害
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      RTECSSZ0199480
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
        Risk Statements
        • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
        • R22 Harmful if swallowed 吞咽有害
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
          Hazard Codes Xn
        • {uni_hamburg} Short: EINECS
        • {uni_hamburg} Short: III/35D2
        • {ALF} The lithiated derivative undergoes Horner olefination reactions with carbonyl compounds to give, after dehydration, vinyl or allyl phosphine oxides: Synthesis, 64 (1988). The reaction has been use in a useful synthesis of (3Z,6E)-ɑ-farnesene: J. Org. Chem., 60, 6211 (1995); for reaction scheme see Geranyl­ bromide, A14093. Epoxides give -hydroxy propylphosphine oxides: J. Chem. Soc., Perkin 1, 2971 (1988); see also: J. Chem. Soc., Perkin 1, 1963 (1999).
        • 2129-89-7 H29828 Methyldiphenylphosphine oxide
甲基二苯基氧化膦

          化学属性

          Mol. FormulaC13H13OP
          Mol. Weight216.22
          Melting Point111-115°C
          TSCANo
          Boiling Point180 °C at 1 mmHg
          Density1.0

          *以上化合物性质及应用等信息仅供参考