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Tris(dibenzylideneacetone)dipalladium-chloroform adduct 三(二亚苄基丙酮)二钯(0)-氯仿络合物

规格: 98%,Pd>20.6%
CAS: 52522-40-4
产品编号: H26700
MDL: MFCD00075479
品牌: INFI
Chemical NameTris(dibenzylideneacetone)dipalladium(0)-chloroform Adduct
CAS Number52522-40-4
Alfabeta NameTRISDIBENZYLIDENEACETONEDIPALLADIUMCHLOROFORMADDUCT ()-
MDL NumberMFCD00075479
Synonym Pd2(dba)3·CHCl3 {LY} Pd2(dba)3·CHCl3 {} {LY} Pd2(dba)3·CHCl3 {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Pd2(dba)3·CHCl3 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID11029508
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation三(二亚苄基丙酮)二钯-氯仿加合物
LabNetwork Molecule IDLN00177555
InChIInChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;/b3*13-11+,14-12+;;;
Canonical SMILES[Pd][Pd].ClC(Cl)Cl.O=C(/C=C/C1=CC=CC=C1)/C=C/C2=CC=CC=C2.[3]
GHS Symbol
Warnings IRRITANT
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
    Risk Statements
    • R22 Harmful if swallowed 吞咽有害
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
    • R38 Irritating to skin 刺激皮肤
    • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
    • R48/20/22
      Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, prote
      WGK Germany3
      Precautionary statements
      • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
        Signal word Warning
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
        • H302 Harmful if swallowed 吞食有害
        • H351 Suspected of causing cancer 怀疑致癌
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Hazard Codes Xn
        • 环化催化剂。
        • {ALF} Phosphine-free Pd(0) catalyst. Catalyzes the addition of arylboronic acids to aldehydes, affording secondary alcohols. No reaction was observed in the absence of chloroform: Org. Lett., 7, 4153 (2005).
        • 52522-40-4 H26700 Tris(dibenzylideneacetone)dipalladium-chloroform adduct	三(二亚苄基丙酮)二钯(0)-氯仿络合物

          化学属性

          Mol. FormulaC52H31Cl3O3Pd2
          Mol. Weight1035
          Melting Point131-135°C
          TSCANo
          Density1.422
          Appearance red to brown solid
          Stabilityair sensitive, moisture sensitive

          *以上化合物性质及应用等信息仅供参考