DoMole-安徽敦茂科技

Triphenylphosphine 三苯基膦

规格: 99.8%

CAS: 603-35-0

产品编号: H18421

MDL: MFCD00003043

品牌: INFI

Chemical Name	Triphenylphosphine
MDL Number	MFCD00003043
CAS Number	603-35-0
EC Number	210-036-0
Beilstein Registry Number	610776
Synonym	Triphenylphosphine {LY} Triphenylphosphine phosphine,triphenyl triphenyl-phosphane triphenyl-phosphin triphenylphosphine triphenylphosphine hydrobromide triphenylphosphine hydrochloride {} {LY} Triphenylphosphine {} {} {LY} Triphenylphosphine {} {} {} {LY} Triphenylphosphine {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenylphosphine {} {} {} {} {} {}
Merck Number	9743
PubChem Substance ID	11776
Chemical Name Translation	三苯基膦
Reaxys-RN	610776
Wiswesser Line Notation	RPR&R
LabNetwork Molecule ID	LN00198869
InChI	InChI=1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
Canonical SMILES	P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

GHS Symbol

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1135 ppm/4H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
   AIHAM* Annual Meeting of American Industrial Hygiene Association.  (Akron,
   OH)  For publisher information, see AIHAAP.  Volume(issue)/page/year:
   -,-,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW,
   Washington, DC 20460)  History unknown.  Volume(issue)/page/year:
   8EHQ-0384-0014

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Tech

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   EPASR* United States Environmental Protection Agency, Office of Pesticides
   and Toxic Subs

Signal word	Warning
WGK Germany	2
Safety Statements
S22 Do not breathe dust 不要吸入粉尘； S24 Avoid contact with skin 避免皮肤接触； S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S37 Wear suitable gloves 戴适当手套； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
R22 Harmful if swallowed 吞咽有害 R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应 R48/20/22 R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
Precautionary statements
P201 Obtain special instructions before use. 使用前获取专门指示。 P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。 P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。 P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。 P273 Avoid release to the environment. 避免释放到环境中。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P281 Use personal protective equipment as required. 使用所需的个人防护装备。 P301+P312 P301+P312+P330 P302+P350 P302+P352 P302+P352+P333+P313+P362+P364 P304+P312 P304+P340 P304+P340+P312 P305+P351+P338 P305+P351+P338+P337+P313 P308+P313 P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。 P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服 P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。 P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。 P330 Rinse mouth. 漱口 P332+P313 P333+P313 P337+P313 P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用 P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。 P403+P233 P405 Store locked up. 上锁保管。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
H302 Harmful if swallowed 吞食有害 H302+H332 H312 Harmful in contact with skin 皮肤接触有害 H315 Causes skin irritation 会刺激皮肤 H317 May cause an allergic skin reaction 可能导致皮肤过敏 H319 Causes serious eye irritation 严重刺激眼睛 H332 Harmful if inhaled 吸入有害 H335 May cause respiratory irritation 可能导致呼吸道刺激 H350 May cause cancer 可能致癌 H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官 H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。 H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECS	SZ3500000
Hazard Codes	Xn
Storage condition	Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {}
UN Number
Warnings	危化品目录(2015)
Packing Group	III
Restrict	-

用于有机合成，聚合引发剂，抗菌素类药物氯洁霉素的原料，有机微量分析测定磷的标准样品。

{ALF} Azides can be converted selectively to amines, in the presence of ester, epoxide or nitro groups, by reduction to iminophosphoranes (Staudinger reaction), followed by hydrolysis. For reviews, see: Tetrahedron, 37, 437 (1981); 48, 1353 (1992):

{ALF} Finds widespread use as a complexing agent with transition metals, either in the preparation of stable complexes, or as an additive in metal-promoted reactions. See also Tri(o-tolyl)phosphine, A12093 and Tri(2-furyl)phosphine, L13329.

{ALF} For use in peptide and other coupling reactions, see 2,2'-Dipyridyl disulfide, A11118.

{ALF} In suitable circumstances, the iminophosphorane may undergo intramolecular aza-Wittig reaction: Tetrahedron, 45, 6375 (1989):

{ALF} Reviews: Aza-Wittig reaction in heterocyclic synthesis: Org. Prep. Proced. Int., 24, 209 (1992); Iminophosphoranes as building blocks for the preparation of N-containing heterocycles: Synthesis, 1197 (1994).

{ALD} Merck: 14,9743

Beilstein:16,759

{ALD} Merck: 14,9743

{ALF} For use in the Mitsunobu reaction for conversion of alcohols to alkylating agents, see N-Guanylurea sulfate, A19106, and Diisopropyl azodicarboxylate, L10386. See also 1,2-Bis(diphenylphosphino)ethane, A11419.

化学属性

Mol. Formula	C18H15P
Mol. Weight	262.29
Density	1.132
Vapor Density	9 (vs air)
Boiling Point	377
Vapor Pressure	5 mmHg ( 20 °C)
Melting Point	79-81
Flash Point	359°F
TSCA	Yes
Solubility	Soluble in ether, acetone, chloroform (50 mg/ml), and alcohol. Insoluble in water.
Stability	对光敏感
Appearance	white xtl.
Danger-Level	乙类
pH	-:-
Redox	-

*以上化合物性质及应用等信息仅供参考

电子化学品

催化剂

配体

有机硅

元素分类

其他精细新材料

Triphenylphosphine 三苯基膦

规格: 99.8%

化学属性

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